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Good news / Bad news for you.
As yet we have no official word in relation to a possible annotated season 6, obviously it may be slightly more difficult with Kim having left, but I would be very surprised if at the very least we don't get a movie length version before the end of the year.
However I have much better news re the DVD - S6 is up for preorder on Amazon for OCT 8th.
In addition and looking mighty tempting is a full six season collection set also scheduled for the 8th. As of yet there's no information as to whether there are any additional features/extras, but the idea of having a boxset that matches the official companion is pretty cool.
PS: Welcome to the G&S Forums.
Love The Guild and/or Choose Your Own Adventure Novels? Then make sure to check out The Trials of Codex.